Synergistic effects of multiwalled carbon nanotubes and Al on the electrochemical hydrogen storage properties of Mg2Ni-type alloy prepared by mechanical alloying |
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Authors: | LW Huang O Elkedim M Nowak M Jurczyk R Chassagnon DW Meng |
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Affiliation: | 1. Faculty of Materials Science and Chemical Engineering, China University of Geosciences, Wuhan 430074, China;2. FEMTO-ST, MN2S, Université de Technologie de Belfort-Montbéliard, Site de Sévenans, 90010 Belfort cedex, France;3. Institute of Materials Science and Engineering, Poznan University of Technology, Sklodowska-Curie 5 Sq., 60-965 Poznan, Poland;4. Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR 5209 CNRS, Université de Bourgogne 9 Av. A. Savary, BP 47870, F-21078 Dijon, France |
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Abstract: | Mg2−xAlxNi (x = 0, 0.25) electrode alloys with and without multiwalled carbon nanotubes (MWCNTs) have been prepared by mechanical alloying (MA) under argon atmosphere at room temperature using a planetary high-energy ball mill. The microstructures of synthesized alloys are characterized by XRD, SEM and TEM. XRD analysis results indicate that Al substitution results in the formation of AlNi-type solid solution that can interstitially dissolve hydrogen atoms. In contrast, the addition of MWCNTs hardly affects the XRD patterns. SEM observations show that after co-milling with 5 wt. % MWCNTs, the particle sizes of both Mg2Ni and Mg1.75Al0.25Ni milled alloys are decreased explicitly. The TEM images reveal that ball milling is a good method to cut long MWCNTs into short ones. These MWCNTs aggregate along the boundaries and surfaces of milled alloy particles and play a role of lubricant to weaken the adhesion of alloy particles. The majority of MWCNTs retain their tubular structure after ball milling except a few MWCNTs whose tubular structure is destroyed. Electrochemical measurements indicate that all milled alloys have excellent activation properties. The Mg1.75Al0.25Ni-MWCNTs composite shows the highest discharge capacity due to the synergistic effects of MWCNTs and Al on the electrochemical hydrogen storage properties of Mg2Ni-type alloy. However, the improvement on the electrode cycle stability by adding MWCNTs is unsatisfactory. |
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Keywords: | Mg2Ni-type alloy Mechanical alloying Multiwalled carbon nanotubes Al substitution Electrochemical hydrogen storage properties |
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