Preparation of a porous carbon from ferrocene-loaded polyaniline and its use in hydrogen adsorption |
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Authors: | Yuanzhen Chen Xiuzhen Cao Haiyan Zhu Yongning Liu |
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Affiliation: | 1. State Key Laboratory for Mechanical Behavior of Materials, School of Material Science and Engineering, Xi’an Jiaotong University, Xi’an 710049, PR China;2. Department of Chemistry and Chemical Engineering, Weinan Teacher’s University, Weinan 714000, PR China |
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Abstract: | A porous carbon made of polyaniline with different ferrocene loadings was prepared through carbonization and thermal chemistry activation with KOH. The ferrocene served as a pore-forming agent and a resource of iron nanoparticles. N2 adsorption/desorption measurements showed that the specific surface area and pore volume ranged from 2681 to 3246 m2 g−1 and from 1.56 to 2.06 cm3 g−1, respectively, with increasing ferrocene loadings. Similarly, hydrogen adsorption also increased from 5.3 to 6.2 wt% at 77 K/5 MPa and 0.6 wt% to 0.85 wt% at 293 K/8 MPa. Scanning electron microscopy, X-ray diffraction and energy dispersive X-ray analysis showed that iron nanoparticles were embedded in the carbon matrix or dispersed on the surface. The large specific surface area and big pore volume improved the original hydrogen adsorption heat up to 7.2 kJ mol−1 for the best sample. |
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Keywords: | Porous carbon Hydrogen adsorption Pore-forming agent |
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