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La-doped SrTiO3 interconnect materials for anode-supported flat-tubular solid oxide fuel cells
Authors:Beom-Kyeong Park  Jong-Won Lee  Seung-Bok Lee  Tak-Hyoung Lim  Seok-Joo Park  Rak-Hyun Song  Won Bin Im  Dong-Ryul Shin
Affiliation:1. Fuel Cell Research Center, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea;2. Department of Advanced Energy Technology, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 305-350, Republic of Korea;3. School of Materials Science and Engineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Republic of Korea
Abstract:An interconnect layer in an anode-supported flat-tubular solid oxide fuel cell connects electrically unit cells and separates fuel from oxidant in the adjoining cells. Nano-sized La-doped SrTiO3 for the interconnect is synthesized in this study by the Pechini method using citric acid. The materials with stoichiometric and Sr-deficient compositions are prepared and sintered in an oxidizing atmosphere. The synthesized fine powders exhibit high sinterability, leading to near-full densification. The Sr deficiency plays a crucial role in mechanical, electrical and thermal expansion properties. The interconnect is coated using the synthesized powder on a porous flat-tubular anode support by a screen printing process. The thin and dense layer is obtained after co-sintering in air, and the interconnect/anode interface remains intact upon reduction.
Keywords:Anode-supported solid oxide fuel cell   Flat-tubular cell   Interconnect   Strontium titanate   Sr deficiency
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