Hydrogen storage by Mg-based nanocomposites |
| |
Authors: | M Jurczyk M Nowak A Szajek A Jezierski |
| |
Affiliation: | 1. Institute of Materials Science and Engineering, Poznan University of Technology, Sklodowska-Curie 5 Sq., 60-965 Poznan, Poland;2. Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17 St., 60-179 Poznan, Poland |
| |
Abstract: | Hydrogen storage materials research is entered to a new and exciting period with the advance of the nanocrystalline alloys, which show substantially enhanced absorption/desorption kinetics, even at room temperatures. In this work, hydrogen storage capacities and the electrochemical discharge capacities of the Mg2(Ni, Cu)-, LaNi5-, ZrV2-type nanocrystalline alloys and Mg2Ni/LaNi5-, Mg2Ni/ZrV2-type nanocomposites have been measured. The electronic properties of the Mg2Ni1-xCux, LaNi5 and ZrV2 alloys were calculated. The nanocomposite structure reduced hydriding temperature and enhanced hydrogen storage capacity of Mg-based materials. The nanocomposites (Mg,Mn)2Ni (50 wt%)-La(Ni,Mn,Al,Co)5 (50 wt%) and (Mg,Mn)2Ni (75 wt%)-(Zr,Ti)(V,Cr,Ni)2.4 (25 wt%) materials releases 1.65 wt% and 1.38 wt% hydrogen at 25 °C, respectively. The strong modifications of the electronic structure of the nanocrystalline alloys could significantly influence hydrogenation properties of Mg-based nanocomposities. |
| |
Keywords: | Magnesium Hydrogen storage Nanocomposites Electronic structure |
本文献已被 ScienceDirect 等数据库收录! |
|