Anhydrous proton conducting polymer electrolytes based on poly(vinylphosphonic acid)-heterocycle composite material |
| |
Authors: | Masanori Yamada |
| |
Affiliation: | Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba, Ibaraki 305-8568, Japan |
| |
Abstract: | The development of anhydrous proton conducting membrane is important for the operation of polymer electrolyte membrane fuel cell (PEMFC) at intermediate temperature (100-200 °C). In this study, we have investigated the acid-base hybrid materials by mixing of strong phosphonic acid polymer of poly(vinylphosphonic acid) (PVPA) with the high proton-exchange capacity and organic base of heterocycle, such as imidazole (Im), pyrazole (Py), or 1-methylimidazole (MeIm). As a result, PVPA-heterocycle composite material showed the high proton conductivity of approximately 10−3 S cm−1 at 150 °C under anhydrous condition. In particular, PVPA-89 mol% Im composite material showed the highest proton conductivity of 7×10−3 S cm−1 at 150 °C under anhydrous condition. Additionally, the fuel cell test of PVPA-89 mol% Im composite material using a dry H2/O2 showed the power density of approximately 10 mW cm−2 at 80 °C under anhydrous conditions. These acid-base anhydrous proton conducting materials without the existence of water molecules might be possibly used for a polymer electrolyte membrane at intermediate temperature operations under anhydrous or extremely low humidity conditions. |
| |
Keywords: | Acid-base composite material Anhydrous proton conductivity Polymer electrolyte membrane fuel cells (PEMFC) |
本文献已被 ScienceDirect 等数据库收录! |
|