Kinetic study on free radical polymerization of alkyl acylamidoacrylates by pulsed laser polymerization using nitrogen laser |
| |
Authors: | Hitoshi Tanaka Takahiko Gohda Akihisa Ohta |
| |
Affiliation: | Department of Optical Science and Technology, Faculty of Engineering, Tokushima University, 2-1 Minamijosanjima-cho, Tokushima 770-8506, Japan |
| |
Abstract: | Radical polymerization of captodatively substituted alkyl acylamidoacrylates was studied by pulsed laser polymerization using a N2 laser. Propagation rate coefficient of the acrylates was varied with solvents used in spite of a radical mechanism, but little varied with methyl, n-propyl, and isopropyl substituents on the acrylates. Arrhenius parameters for the propagation indicated that a solvent affected mostly on a frequency factor rather than a activation energy. In addition, it was suggested that these captodatively substituted propagating radicals were thermodynamically persistent but kinetically active in propagation, which resulted in rather smooth propagation in spite of bulky 1,1-disubstituted olefins. The mechanism of the polymerizations was discussed in detail on the basis of the kinetic studies and ESR spectroscopy. |
| |
Keywords: | Radical polymerization Pulsed laser polymerization Captodative |
本文献已被 ScienceDirect 等数据库收录! |
|