High structural retention during pulsed plasma polymerization of 1H,1H,2H-perfluorododecene: an NMR and TOF-SIMS study |
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| Authors: | EJ Kinmond JPS Badyal SA Brewer |
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| Affiliation: | a Department of Chemistry, Science Laboratories, Durham University, Durham DH1 3LE, UK
b Dstl, Porton Down, Salisbury SP4 OJQ, UK |
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| Abstract: | A combined NMR and TOF-SIMS study has been carried out on 1H,1H,2H-perfluorododecene plasma polymers. Pulsed plasma polymerization is found to give rise to a high level of structural retention for the perfluoroalkyl groups, whereas continuous wave conditions lead to monomer fragmentation and cross linking. This investigation provides unequivocal proof that pulsed plasma deposition is a simple and highly effective method for functionalising solid surfaces. |
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| Keywords: | Fluoropolymer Coating Plasma |
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