Effect of Reaction Parameters on γ-AlON Formation from Al2O3 and AlN |
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Authors: | Siddhartha Bandyopadhyay,Georg Rixecker,Fritz Aldinger,&Dagger ,Sushanta Pal,Keka Mukherjee,Himadri Sekhar Maiti |
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Affiliation: | Central Glass and Ceramic Research Institute, Kolkata 700 032, India;Pulvermetallurgisches Laboratorium, Max-Planck-Institüt für Metallforschung and Institüt für Nichtmetallische Anorganische Materialen der Universitat Stuttgart, 70569 Stuttgart, Germany |
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Abstract: | The formation of γ-AlON from Al2O3 and AlN was investigated as a function of some of the reaction parameters, that is, temperature and time. The appearance of phases was followed in conjunction with the change in lattice parameter to reveal the reaction sequences of formation. An oxygen-rich γ-AlON phase formed first, which reacted further with AlN. Nitrogen diffusion through the γ-AlON lattice seemed to be rate controlling. |
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Keywords: | aluminum oxynitride reaction rate optical materials/properties |
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