| Sm填充方钴矿化合物的合成及热电性能 |
| |
| 引用本文： | 宋晨,唐新峰,刘桃香,张清杰. Sm填充方钴矿化合物的合成及热电性能[J]. 武汉理工大学学报, 2007, 29(2): 1-4 |
| |
| 作者姓名： | 宋晨 唐新峰 刘桃香 张清杰 |
| |
| 作者单位： | 武汉理工大学材料复合新技术国家重点实验室,武汉,430070 |
| |
| 基金项目： | 国家自然科学基金;高等学校博士学科点专项科研项目 |
| |
| 摘 要： | 采用高温熔融法结合固相反应法合成了一系列单相的SmyFexCo4-x-Sb12化合物，并探索了Sm填充分数对其热电性能的影响规律。结果表明，随着Sm填充分数的增加，载流子浓度及电导率降低；塞贝克系数随温度的升高和Sm填充分数的增加而增大；晶格热导率随Sm填充分数的增加先减小然后再增加，在某一填充分数时达到最小值。Sm0．19Fe1.47Co2．53Sb12化合物显示最大热电性能指数，在750K时其最大无量纲热电性能指数ZTmax值达0．55。
|
| 关 键 词： | 填充式方钴矿 电导率 晶格热导率 热电性能 |
| 文章编号： | 1671-4431(2007)02-0001-04 |
| 修稿时间： | 2006-10-13 |
The Synthesis and Thermoelectric Properties of Samarium-filled Skutterudite SmyFexCo4-xSb12 |
| |
| SONG Chen,TANG Xin-feng,LIU Tao-xiang,ZHANG Qing-jie. The Synthesis and Thermoelectric Properties of Samarium-filled Skutterudite SmyFexCo4-xSb12[J]. Journal of Wuhan University of Technology, 2007, 29(2): 1-4 |
| |
| Authors: | SONG Chen TANG Xin-feng LIU Tao-xiang ZHANG Qing-jie |
| |
| Abstract: | The single-phase SmyFexCo4-xSb12 compounds were synthesized by using the solid-state reaction method and melting reaction method,and the thermoelectric properties of SmyFexCo4-xSb12 were investigated.Research results indicated that the electrical conductivity of SmyFexCo4-xSb12 decreased with increasing Sm filling fraction,which the carrier concentration dramatically depends on.Seebeck coefficient increased with increasing temperature and Sm filling fraction.The lattice thermal conductivity decreased evidently with increasing Sm filling fraction,and reached the minimum value at a certain Sm filling fraction.The maximum figure of merit ZTmax of Sm0.19Fe1.47Co2.53Sb12 is 0.55 at 750 K. |
| |
| Keywords: | filled-skutterudite electrical conductivity lattice thermal conductivity thermoelectric performance |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
