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Content,composition, and stereochemical characterisation of lignans in berries and seeds
Authors:Annika I Smeds  Patrik C Eklund  Stefan M Willför
Affiliation:1. Laboratory of Wood and Paper Chemistry, Process Chemistry Centre, Åbo Akademi University, Porthansgatan 3-5, FI-20500 Turku/Åbo, Finland;2. Laboratory of Organic Chemistry, Åbo Akademi University, Biskopsgatan 8, FI-20500 Turku/Åbo, Finland
Abstract:In seed extracts of five oilseed species, in bran extracts of three cereal species, and in seed and/or whole berry extracts of 10 berry species, the concentrations of a large number of lignans and the enantiomeric composition of selected lignans were determined. In the case of sesame and hemp seeds, the lignan content and composition of the whole seeds was compared to that of the hulled seeds. The results showed that cloudberry seeds are the third most lignan-rich food source after linseeds and whole sesame seeds, and that most of the berry species analysed were more lignan-rich than the cereal brans. The lignans are concentrated in the hull of the oilseeds and in the seeds of the berries. In most samples, secoisolarici-, pino-, medio-, and syringaresinol were present as a mixture of two enantiomers.
Keywords:Lignans  Lignan enantiomers  Chiral HPLC  Mass spectrometry  LC&ndash  MS  Bran  Seeds  Seed hull  Berries
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