| 茂金属化合物催化极性烯类单体活性聚合的研究进展 |
| |
| 引用本文： | 孔媛,马利福,黄启谷,赵杨锋,李俊拢,汪红丽,邓坤学,盛亚平,义建军,汪威,杨万泰.茂金属化合物催化极性烯类单体活性聚合的研究进展[J].化工进展,2009,28(2). |
| |
| 作者姓名： | 孔媛 马利福 黄启谷 赵杨锋 李俊拢 汪红丽 邓坤学 盛亚平 义建军 汪威 杨万泰 |
| |
| 作者单位： | 孔媛,马利福,黄启谷,赵杨锋,李俊拢,汪红丽,邓坤学,盛亚平,杨万泰,KONG Yuan,MA Lifu,HUANG Qigu,ZHAO Yangfeng,LI Junlong,WANG Hongli,DENG Kunxue,SHENG Yaping,YANG Wantai(北京化工大学化学资源有效利用国家重点实验室,北京,100029);义建军,汪威,YI Jianjun,WANG Wei(中国石油石油化工研究院,北京,100083)
|
| |
| 基金项目： | 国家自然科学基金，中石油风险基金，北京市教委重点学科共建项目 |
| |
| 摘 要： | 综述了CGC催化剂、单茂催化剂、多核茂金属催化剂、桥联茂金属催化剂,非茂金属催化剂催化极性烯类单体均聚合及极性烯类单体与非极性烯类单体共聚合的研究.茂金属催化剂催化极性烯类单体聚合的机理包括配位聚合机理与活性自由基聚合机理.采用茂金属催化体系可以制备极性烯类单体的均聚物及极性烯类单体与非极性烯类单体的共聚物.不仅拓宽了茂金属催化剂的应用范围,而且可开发出具有新性能的极性聚烯烃树脂.
|
| 关 键 词： | 茂金属催化剂 极性烯类单体 活性配位聚合 活性自由基聚合 极性聚烯烃树脂 |
Advances in living polymerization of polar monomers promoted by metallocene complexes |
| |
| KONG Yuan,MA Lifu,HUANG Qigu,ZHAO Yangfeng,LI Junlong,WANG Hongli,DENG Kunxue,SHENG Yaping,YI Jianjun,WANG Wei,YANG Wantai.Advances in living polymerization of polar monomers promoted by metallocene complexes[J].Chemical Industry and Engineering Progress,2009,28(2). |
| |
| Authors: | KONG Yuan MA Lifu HUANG Qigu ZHAO Yangfeng LI Junlong WANG Hongli DENG Kunxue SHENG Yaping YI Jianjun WANG Wei YANG Wantai |
| |
| Affiliation: | 1State Key Laboratory of Chemical Resource Engineering;College of Materials Science and Engineering;Beijing University of Chemical Technology;Beijing 100029;China;2 Research Institute of Petrochemical Technology;China National Petroleum Corporation;Beijing 100083;China |
| |
| Abstract: | The advances in homopolymerization of polar monomers and copolymerization of nonpolar monomers with polar monomers based on CGC catalyst,half-metallocene catalyst,bis-metallocene catalyst,multinuclear metallocene catalyst,bridged metallocene catalyst,and non-metallocene catalyst are reviewed. The mechanism of polar monomer polymerization promoted by metallocene catalysts includes living radical polymerization and coordination polymerization.Polymer of polar monomer and copolymer of polar monomer with nonpol... |
| |
| Keywords: | metallocene catalyst polar monomer living coordination polymerization living radical polymerization polar polyolefin resin |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
