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鼓泡塔中水合物法分离混合气体的数值模拟
引用本文:罗艳托,朱建华,陈光进.鼓泡塔中水合物法分离混合气体的数值模拟[J].中国化学工程学报,2007,15(3):345-352.
作者姓名:罗艳托  朱建华  陈光进
作者单位:[1]Faculty of Chemical science & Engineering, China University of Petroleum, Beijing 102249, China [2]PetroChina Planning & Engineering Institute, Beijing 100083, China
摘    要:To develop a new technique for separating gas mixtures via hydrate formation,a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the ex- perimental bubble column reactor,assuming that the liquid phase was in the axial dispersion regime and the gas phase was in the plug flow regime,in the presence of hydrate promoter tetrahydrofuran(THF),the rate of hydrogen enrichment for CH4+H2 gas mixtures at different operational conditions(such as temperature,pressure,concentra- tion of gas components,gas flow rate,liquid flow rate)were simulated.The heat product of the hydrate reaction and its axial distribution under different operational conditions were also calculated.The results would be helpful not only to setting and optimizing operation conditions and design of multi-refrigeration equipment,but also to hydrate separation technique industrialization.

关 键 词:鼓泡塔  水合物法分离  混合气体  数值模拟
收稿时间:23 May 2006
修稿时间:2006-05-232006-12-11

Numerical simulation of separating gas mixtures via hydrate formation in bubble column
LUO Yantuo,ZHU Jianhua,CHEN Guangjin.Numerical simulation of separating gas mixtures via hydrate formation in bubble column[J].Chinese Journal of Chemical Engineering,2007,15(3):345-352.
Authors:LUO Yantuo  ZHU Jianhua  CHEN Guangjin
Affiliation:Faculty of Chemical Science & Engineering, China University of Petroleum, Beijing 102249, China;PetroChina Planning & Engineering Institute, Beijing 100083, China;Faculty of Chemical Science & Engineering, China University of Petroleum, Beijing 102249, China
Abstract:To develop a new technique for separating gas mixtures via hydrate formation, a set of medium-sized experimental bubble column reactor equipment was constructed.On the basis of the structure parameters of the experimental bubble column reactor, assuming that the liquid phase was in the axial dispersion regime and the gas phase was in the plug flow regime, in the presence of hydrate promoter tetrahydrofuran (THF), the rate of hydrogen enrichment for CH4 H2 gas mixtures at different operational conditions (such as temperature, pressure, concentration of gas components, gas flow rate, liquid flow rate) were simulated.The heat product of the hydrate reaction and its axial distribution under different operational conditions were also calculated.The results would be helpful not only to setting and optimizing operation conditions and design of multi-refrigeration equipment, but also to hydrate separation technique industrialization.
Keywords:hydrate  kinetics  separation  bubble column  numerical simulation
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