| 固体超强酸树脂催化合成邻苯二甲酸二甲酯的工艺研究 |
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| 引用本文： | 林洵,;陈建福.固体超强酸树脂催化合成邻苯二甲酸二甲酯的工艺研究[J].化工技术与开发,2014(5):14-17. |
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| 作者姓名： | 林洵 ;陈建福 |
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| 作者单位： | [1]漳州职业技术学院食品与生物工程系,福建漳州363000; [2]福州大学化学化工学院,福建福州350108 |
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| 基金项目： | 福建省教育厅科技计划项目（JB13294）; 漳州市自然科学基金（ZZ2013J07）; 漳州职业技术学院科技计划项目（ZZY1304） |
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| 摘 要： | 以固体超强酸树脂为催化剂合成了邻苯二甲酸二甲酯,分别对醇酸摩尔比、催化剂用量、反应温度、反应时间进行单因素和正交试验,并通过极差和方差分析对酯化过程中显著影响酯化率的因素进行统计分析。结果表明最佳的合成工艺条件为:醇酸摩尔比4.5、催化剂用量2.5%、反应温度115℃、反应时间160min,在此工艺条件下酯化率可达99.5%。该催化剂具有良好的耐磨性,可重复使用。
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| 关 键 词： | 邻苯二甲酸二甲酯 酯化率 固体超强酸树脂 催化 |
Synthesis of Dimethyl Phthalate Catalyzed by Solid Superacid |
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| Affiliation: | LIN Xun, CHEN Jian-fu (1 .Department of Food and Biology Engineering, Zhangzhou Institute of Technology, Zhangzhou 363000, China; 2.College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China) |
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| Abstract: | The dimethyl phthalate was synthesized which catalyzed by solid super acid resin. The effects of radio of alcohol to acid, catalyst dosage, reaction temperature and reaction time on esterifi cation yield were investigated by single factor test and orthogonal array design methods. And the notability difference was analyzed by statistic method of range and variance. Results showed that the optimal conditions were as followed： the ratio of alcohol to acid was 4.5,the catalyst dosage was 2.5%, the reaction temperature was 115℃ and the reaction time was 160min. Under the optimal conditions, the esterifi cation yield was reached up to 99.5%. The wear resistance of catalyst was excellent and could be reused. |
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| Keywords: | dimethyl phthalate esterifi cation yield solid superacid catalyst |
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