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Quenching of photocatalytic activity and enhancement of photostability of ZnO particles by polydimethysiloxane coating
Authors:Myung-Geun Jeong  Hyun Ook Seo  Kwang-Dae Kim  Dae Han Kim  Young Dok Kim  Dong Chan Lim
Affiliation:(1) Department of Chemistry, Sungkyunkwan University, Suwon, 440-746, Korea;(2) Materials Processing Division, Korea Institute of Materials Science, Changwon, 641-010, Korea;
Abstract:ZnO particles with a size range of 50–150 nm were coated with polydimethylsiloxane (PDMS) with a thin film thickness of 3–4 nm using a simple ambient-pressure chemical vapor deposition method. Surfaces consisting of the PDMS-coated ZnO nanoparticles were found to be superhydrophobic with a water contact angle >160°. The superhydrophobicity was sustained in the presence of UV light. Photocatalytic activity and photocorrosion of ZnO were nearly completely quenched in the presence of PDMS-coating. It is suggested that our PDMS-coating can be of potential interest for the application of ZnO in UV protection agents and energy and electronic devices.
Keywords:
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