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Influence of spin orbit coupling and lanthanide contraction on the exchange interaction in rare earth garnets
Authors:C M Srivastava  C Srinivasan  R Aiyar
Affiliation:(1) Department of Physics, Indian Institute of Technology, 400 076 Bombay, India
Abstract:The exchange constants observed in the rare earth iron garnets, obtained from fitting magnetization and paramagnetic susceptibility as a function of temperature have been analysed in terms of Anderson’s theory of superexchange. The transfer integrals and covalency parameters have been obtained for various rare earth ions overlapping with oxygen.
Keywords:Exchange constants  superexchange  transfer integrals  covalency parameters  molecular field constants
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