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Modeling continuous electropermutation with effects of water dissociation included |
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| Authors: | Carl‐Ola Danielsson Anders Dahlkild Anna Velin Mårten Behm |
| Affiliation: | 1. Dept. of Mechanics, School of Engineering Science, Royal Institute of Technology, Stockholm, SE‐100 44, Sweden;2. Vattenfall Research and Development AB, Stockholm, SE‐162 87, Sweden;3. Applied Electrochemistry, Dept. of Chemical Engineering and Technology, School of Chemical Science and Engineering, Royal Institute of Technology, Stockholm, SE‐100 44, Sweden |
| Abstract: | The repeating unit consisting of a cell pair of one concentrate and one feed compartment of an electropermutation stack is modeled. Both the feed and the concentrate compartments are filled with an ion‐exchange textile material. Enhanced water dissociation taking place at the surface of the membrane is included in the model as a hetrogeneous surface reaction. Results from simulations of nitrate removal for drinking water production are presented and comparisons with previous experimental results are made. The influence of both conductive and inert textile spacers on the process is investigated via simulations. © 2010 American Institute of Chemical Engineers AIChE J, 2010 |
| Keywords: | ion exchange mathematical modeling membrane separations electrochemistry simulation process |