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Bio‐inspired Photoelectric Conversion Based on Smart‐Gating Nanochannels
Authors:Liping Wen  Xu Hou  Ye Tian  Jin Zhai  Lei Jiang
Affiliation:1. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (P.R. China);2. National Center for Nanoscience and Technology, Beijing 100190 (P.R. China);3. Beijing University of Aeronautics and Astronautics, Beijing 100191 (P.R. China)
Abstract:Inspired by the light‐driven, cross‐membrane proton pump of biological systems, a photoelectric conversion system based on a smart‐gating, proton‐driven nanochannel is constructed. In this system, solar energy is the only source of cross‐membrane proton motive force that induces a diffusion potential and photocurrent flowing through the external circuit. Although the obtained photoelectric conversion performance is lower than that of conventional solid photovoltaic devices, it is believed that higher efficiencies can be generated by enhancing the protonation capacity of the photo‐acid molecules, optimizing the membrane, and synthesizing high‐performance photosensitive molecules. This type of facile and environmentally friendly photoelectric conversion has potential applications for future energy demands such as the production of power for in vivo medical devices.
Keywords:bioelectronics  nanochannels  charge transport  electro‐optical materials  photovoltaic devices
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