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Effect of silicate solutions on metakaolinite based cementitious materia
引用本文:肖雪军 李化建 孙恒虎. Effect of silicate solutions on metakaolinite based cementitious materia[J]. 煤炭学报(英文版), 2006, 12(1): 25-28
作者姓名:肖雪军 李化建 孙恒虎
作者单位:[1]Department of Resources, China University of Mining & Technology (Beijing), Beijing 100083,China [2]Department of Material Science and Engineering, Tsinghua University, Beijing 100084, China
基金项目:Supported by the National 863 Plan Project of China(2003AA332020); National Natural Science Foundation of China(50474002) and Key Project of Ministry of Education of China( 104231)
摘    要:High performance metakaolinite based cementitious materials were prepared with metakaolinite as main component, and the different modules of Na and Na-K silicate solutions as diagenetic agent. The results show that the mechanical properties are affected by different silicate solutions, compressive strengths of pastes hydrated for 3 d and 28 d with Na-K silicate solution (The modulus is 1) are about 43.68 and 78.52 MPa respectively. By analyzing the mechanical properties of Metakaolinite based cementitious materials, the diagenetic effect of lower module is better than higher module, and Na-K silicate solution is better than Na silicate solution. The structure of the Na and Na-K silicate solutions is studied with IR and 29Si NMR, the reason of the lower module and Na-K silicate solution improving the mechanical properties is that the low module silicate solution has lower polymeric degree of silicon dioxide, and the higher polymeric degree of silicon oxide tetrahedron(Q^4) in Na-K silicate solution is less than Na silicate solution.

关 键 词:二水高岭石 粘结材料 机械性能 硅酸盐水泥

Effect of silicate solutions on metakaolinite based cementitious materia
XIAO Xue-jun, LI Hua-jian, SUN Heng-hu , Beijing ,China;. Effect of silicate solutions on metakaolinite based cementitious materia[J]. Journal of Coal Science & Engineering(China), 2006, 12(1): 25-28
Authors:XIAO Xue-jun, LI Hua-jian, SUN Heng-hu , Beijing ,China  
Affiliation:XIAO Xue-jun, LI Hua-jian, SUN Heng-hu , Beijing 100083,China; 2. Department of Material Science and Engineering, Tsinghua University, Beijing 100084, China)
Abstract:
Keywords:metakaolinite   cementitious materials   mechanical properties
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