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毛细管色谱测定裂解原料及其产物
引用本文:项敏,刘广荣,袁明.毛细管色谱测定裂解原料及其产物[J].石油化工,1986(2).
作者姓名:项敏  刘广荣  袁明
作者单位:北京燕山石油化工公司研究院,北京燕山石油化工公司研究院,北京燕山石油化工公司研究院
摘    要:建立了质谱及HPIC测定轻柴油族组成的方法,并用毛细管邑谱对裂解原料及产物气态烃、裂解汽油及裂解焦油诸组份进行分离,用保留指数、色-质联用、加氢反应等手段定性,用峰面积归一法定量。在30万吨乙烯装置考核中应用,数据符合工艺实际情况。


Analysis of Light Gas Oil and Its Pyrolysis Products by Capillary Gas Chromatography
Abstract:Methods for analyzing hydrocarbon group type by mass spectrometry and HPLC were established. The composition of the light gas oil feedstock for olefine production and the pyrolysis products such as light hydrocarbons, pyrolysis gasoline and fuel oil were determined quantitatively by capillary GC and qualitatively by retention indices, GC-MS etc. These methods were applied to plant sample analysis, the accuracy and reproducibility were satisfactory.
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