| 四苯基卟啉和金属卟啉的制备 |
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| 引用本文： | 杨彪,刘云,肖德宝. 四苯基卟啉和金属卟啉的制备[J]. 精细化工, 1998, 0(1) |
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| 作者姓名： | 杨彪 刘云 肖德宝 |
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| 作者单位： | 北京轻工业学院科研处(杨彪)，北京轻工业学院化工系(刘云)，鞍山师范学院化学系(肖德宝) |
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| 摘 要： | 采用二甲苯为溶剂，对硝基苯甲酸催化，苯甲醛和吡咯反应合成四苯基卟啉（ＴＰＰ），产率可达５５４％；另外，用ＤＭＦ为溶剂，ＴＰＰ与醋酸锌反应生成金属卟啉锌（ＴＰＰＺｎ），产率可达９７６％。
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| 关 键 词： | 卟啉，金属化卟啉，合成 |
Synthesis of Tetraphenylporphyrin and Metalloporphyrin |
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| Yang Biao. Synthesis of Tetraphenylporphyrin and Metalloporphyrin[J]. Fine Chemicals, 1998, 0(1) |
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| Authors: | Yang Biao |
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| Abstract: | The improved method of preparing porphyrin has been described. Pyrrole and benzaldehyde react in xylene with the catalysis of p nitrobenzonic acid to prepare meso tetraphenylporphyrin(TPP) with the yield 55.4%.This yield is higher than those of other reported methods(20%～60%).Then,refluxed in DMF,TPP and zincacetate give a yield of metalloporphyrin 97.6%. |
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| Keywords: | porphyrin metalloporphyrin synthesis |
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