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Preparation and properties of CdS thin films grown by ILGAR method
作者姓名:QIUJijun  JINZhengguo  WUWeibing  LIUXiaoxin  CHENGZhijie
作者单位:KeyLaboratoryforAdvancedCeramicsandMachiningTechnologyofMinistryofEducation,SchoolofMaterials,TlanjinUniversity,Tianjin300072,China
摘    要:CdS thin films were deposited by the ion layer gas reaction (ILGAR) method. Structural, chemical, topographical development as well as optical and electrical properties of as-deposited and annealed thin films were investigated by XRD,SEM, XPS, AFM and UV-VIS. The results showed that the thin films are uniform, compact and good in adhesion to the substrates, and the growth of the films is 2.8 nm/cycle. The evolution of structure undergoes from the cubic structure to the hexagonal one with a preferred orientation along the (002) plane after annealing at 673 K. An amount of C, O and C1 impudries can be reduced by increasing the drying temperature or by annealing in N2 atmosphere. It was found that the band gap of the CdS films shifts to higher wavelength after annealing or increasing film thickness. The electrical resistivity decreases with increasing annealing temperature and film thickness.

关 键 词:CdS薄膜  ILGAR方法  薄膜材料  生长工艺

Preparation and properties of CdS thin films grown by ILGAR method
QIUJijun JINZhengguo WUWeibing LIUXiaoxin CHENGZhijie.Preparation and properties of CdS thin films grown by ILGAR method[J].Rare Metals,2004,23(4):311-316.
Authors:QIU Jijun  Jin Zhengguo  WU Weibing  Liu Xiaoxin  Cheng Zhijie
Affiliation:Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials, Tianjin University, Tianjin 300072,China
Abstract:CdS thin films were deposited by the ion layer gas reaction (ILGAR) method. Structural, chemical, topographical development as well as optical and electrical properties of as-deposited and annealed thin films were investigated by XRD, SEM, XPS, AFM and UV-VIS. The results showed that the thin films are uniform, compact and good in adhesion to the substrates, and the growth of the films is 2.8 run/cycle. The evolution of structure undergoes from the cubic structure to the hexagonal one with a preferred orientation along the (002) plane after annealing at 673 K. An amount of C, O and Cl impurities can be reduced by increasing the drying temperature or by annealing in N2 atmosphere. It was found that the band gap of the CdS films shifts to higher wavelength after annealing or increasing film thickness. The electrical resistivity decreases with increasing annealing temperature and film thickness.
Keywords:CdS thin film  preparation and properties  ILGAR method  annealing
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