Blue emission of a 2D non-interpenetrated zinc coordination polymer constructed through saturated fatty acid ligand |
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| Affiliation: | 1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, PR China;2. Key Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China;3. Hubei Normal University, Institute for Advanced Materials, Cihu Road, Huangshi, PR China;1. Department of Chemistry, Sree Narayana College, Chempazhanthy, Thiruvananthapuram, Kerala, India-695587;2. Department of Chemistry, Sree Narayana College, Nattika, Thrissur, Kerala, India-680566 |
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| Abstract: | We report a new non-interpenetrated 2D zinc coordination polymer, [Zn(AA)(BPHY)]n (1) (H2AA = adipic acid, BPHY = 1,2-bis(4-pyridyl)hydrazine), which is a mixed ligand complex. The solid-state sample of 1 exhibits tunable blue emission excited by UV light with the wavelengths from 320 nm to 380 nm. The luminescent mechanism of 1 has been studied by theoretical calculation. |
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