| 硫基烯烃的合成新方法 |
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| 引用本文： | 蔡喜田,邓佩佩,郑占伟.硫基烯烃的合成新方法[J].河北化工,2012,35(3):33-34,51. |
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| 作者姓名： | 蔡喜田 邓佩佩 郑占伟 |
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| 作者单位： | 华北制药集团新药研究开发有限责任公司,微生物药物国家工程研究中心,河北石家庄050015 |
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| 摘 要： | 硫基烯烃是具有一定活性的烯类化合物,介绍了硫基烯烃的合成新方法——金属络合物催化法和碱催化法。金属络合物催化和碱催化的含硫化合物与炔烃反应可生成立体选择性、高效性产物,是近年来研究催化法的热点,为碳-硫的构建提供了有效途径。
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| 关 键 词： | 金属络合物 催化 碱催化 硫基烯烃 炔烃 催化 合成 |
New Synthetic Methods of Sulfur-olefin |
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| CAI Xi-tian,DENG Pei-pei,ZHENG Zhan-wei.New Synthetic Methods of Sulfur-olefin[J].Hebei Chemical Engineering and Industry,2012,35(3):33-34,51. |
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| Authors: | CAI Xi-tian DENG Pei-pei ZHENG Zhan-wei |
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| Affiliation: | (NCPC New Drug R & D Co.,Ltd,National Engineering Reasearch Center of Microbial Medicine,Shijiazhuang 050015,China) |
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| Abstract: | Sulfur-olefin is a certain activity of vinyl compound.To introduce its new synthetic methods which are metal complexes-mediated catalysis and base-mediated catalysis.Metal complexes-mediated catalysis and base-mediated catalysis were used to prepared stereo selectivity,high efficiency sulfur based olefins by sulfur compounds and alkynes,and which provided an effective way for the formimg of C-S. |
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| Keywords: | metal complexes-mediated catalysis base-mediateel catalysis sulfur-olefin alkyne catalysis synthesis |
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