| 甲醇合成气中羰基金属化合物对催化剂的影响及对策 |
| |
| 引用本文： | 李选志,弥永丰.甲醇合成气中羰基金属化合物对催化剂的影响及对策[J].工业催化,2006,14(10):28-30. |
| |
| 作者姓名： | 李选志 弥永丰 |
| |
| 作者单位： | 西北化工研究院,陕西,西安,710600;陕西华山化工集团有限公司,陕西,华县,714010 |
| |
| 摘 要： | 羰基铁和羰基镍是铜基合成甲醇催化剂的毒物。论述了羰基铁和羰基镍的形成机理及对甲醇催化剂的影响，指出使用脱羰基铁、羰基镍吸附剂是延长催化剂使用寿命、增加甲醇产量和提高甲醇产品质量的有效措施。
|
| 关 键 词： | 合成气 羰基金属 甲醇催化剂 吸附剂 |
| 文章编号： | 1008-1143（2006）10-0028-03 |
| 收稿时间： | 2006-04-10 |
| 修稿时间： | 2006-06-19 |
Influence of metal carbonyl in synthesis gas on methanol synthesis catalysts and the countermeasures |
| |
| LI Xuan-zhi,MI Yong-feng.Influence of metal carbonyl in synthesis gas on methanol synthesis catalysts and the countermeasures[J].Industrial Catalysis,2006,14(10):28-30. |
| |
| Authors: | LI Xuan-zhi MI Yong-feng |
| |
| Affiliation: | 1.Nor;thwest Research Institute of Chemical Industry, Xi'an 710600, Shaanxi,China;2.;Shaanxi Huashan Chemical Group Co.,Ltd., Huaxian 714010,Shaanxi,China |
| |
| Abstract: | Iron and nickel carbonyl compounds are poisons to copper-based methanol synthesis catalysts.The mechanism for formation of iron and nickel carbonyls and their influence on methanol synthesis catalysts were reviewed.It was pointed out that adoption of sorbents to remove iron and nickel carbonyl was an effective way to protect synthesis catalysts. |
| |
| Keywords: | synthesis gas metal carbonyl methanol synthesis catalyst sorbent |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《工业催化》浏览原始摘要信息 |
|
点击此处可从《工业催化》下载全文 |
