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Titania and titania-silver nanoparticle deposits made by Liquid Flame Spray and their functionality as photocatalyst for organic- and biofilm removal
Authors:Helmi Keskinen  Jyrki M. Mäkelä  Mikko Aromaa  Jorma Keskinen  Sami Areva  Cilâine V. Teixeira  Jarl B. Rosenholm  Viljami Pore  Mikko Ritala  Markku Leskelä  Mari Raulio  Mirja S. Salkinoja-Salonen  Erkki Levänen  Tapio Mäntylä
Affiliation:1. Institute of Physics, Tampere University of Technology, P.O. Box 692, FIN-33101, Tampere, Finland
2. Department of Physical Chemistry, ?bo Akademi University Porthansgatan 3–5, FIN-20500, Turku, Finland
3. Laboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, P.O. Box 55, FIN-00014, Helsinki, Finland
4. Department of Applied Chemistry and Microbiology, University of Helsinki, P.O. Box 56, FIN-00014, Helsinki, Finland
5. Institute of Material Sciences, Tampere University of Technology, P.O. Box 589, FIN-33101, Tampere, Finland
Abstract:Titania and titania-silver nanoparticle deposits were made by Liquid Flame Spray technique, in which the liquid precursor is injected into a high temperature flame, where it will evaporate and nucleate to nanosize particles. One-step and two-step methods were used for preparation of titania-silver deposits. The amount of silver added was 1 wt%. The deposits were collected in the flame zone on steel and glass surfaces and were analyzed by TEM, EDS, XPS and SAXS. The titania deposits consisted of porous nanosized titania agglomerates of primary particles (~10 nm). With silver addition, small spherical silver metal particles (~2 nm) were detected on the agglomerates. An increase in the photocatalytic activity was verified by stearic acid decomposition and biofilm removal using Deinococcus geothermalis as the model organism.
Keywords:liquid flame spray  deposits  photocatalyst  titanium dioxide
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