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循环钢渣与铜渣搭配利用的碳热还原
引用本文:张 俊,戴晓天,严定鎏,齐渊洪.循环钢渣与铜渣搭配利用的碳热还原[J].钢铁,2015,50(12):114-118.
作者姓名:张 俊  戴晓天  严定鎏  齐渊洪
作者单位:钢铁研究总院先进钢铁流程及材料国家重点试验室, 北京 100081
基金项目:河北省自然科学基金项目;国家科技支撑计划
摘    要: 通过理论分析,提出了铜渣与钢渣搭配利用的新工艺,并通过试验考察了含碳球团的还原和熔分情况,探讨了该工艺的可行性。铜渣和钢渣互为熔剂,促进了相互的还原过程,碱度为2.0时最有利于磷的还原,1 400 ℃还原30 min时磷的气化脱除率约为75%;碱度为1.0时最有利于铁氧化物的还原,1 200 ℃还原20 min时试样的金属化率达到92%。铜渣与钢渣的质量之比高于1.32时可以实现渣、铁分离,碱度为1.0时粒铁的收得率超过90%,磷在粒铁中的分布率接近45%。

关 键 词:铜渣  钢渣  还原熔分  铁收得率  脱磷  
收稿时间:2015-03-05

Carbothermic reduction for collocation use between circulating steelmaking slag and copper slag
ZHANG Jun,DAI Xiao-tian,YAN Ding-liu,QI Yuan-hong.Carbothermic reduction for collocation use between circulating steelmaking slag and copper slag[J].Iron & Steel,2015,50(12):114-118.
Authors:ZHANG Jun  DAI Xiao-tian  YAN Ding-liu  QI Yuan-hong
Affiliation:State Key Laboratory of Advanced Steel Processes and Products, Central Iron and Steel Research Institnte, Beijing, 100081, China
Abstract:A new process for collocation use between copper slag and steelmaking slag was proposed based on theoretical analysis, and the reduction as well as smelting-separation situation of carbon composite pellets was investigated by experiments to discuss the feasibility of this process. The copper slag and steelmaking slag promoted mutual reduction process as fluxing agents, and an alkalinity of 2.0 was most beneficial for the reduction of phosphorus, which removal rate was nearby 75% at 1 400 ℃ for 30 minutes. Moreover, the optimal alkalinity for iron oxides reduction was 1.0, the metallization ratio of which reached 92% at 1 200 ℃ for 20 minutes. The separation of iron from molten slag succeeded as the mass ratio of copper slag to steelmaking slag was higher than 1.32, and an iron yield exceeded 90% at the alkalinity of 1.0. Besides, the distribution rate of phosphorus within iron was closed to 45%.
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