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Biodegradable poly(propylene carbonate)/montmorillonite nanocomposites prepared by direct melt intercalation
Affiliation:1. Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China;2. CFHI Tianjin C-E Electrical Automation Co. Ltd, Tianjin 300457, China;3. School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072, China;1. School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, China;2. Analytical & Testing Center, Sichuan University, Chengdu 610064, China;3. School of Chemistry and Chemical Engineering, Analytical and Testing Center, Guangzhou University, Guangzhou 510006, China
Abstract:Intercalation-exfoliated nanocomposites derived from poly(propylene carbonate) (PPC) and organo-modified montmorillonite (OMMT) were prepared by direct melt blending in an internal mixer. The nano-scale dispersion of the OMMT layers within the PPC matrix was verified using wide angle X-ray scattering and transmission electron microscopy technologies. Static mechanical properties were determined by using a tensile tester. The PPC/OMMT nanocomposites with lower OMMT content showed an increase in thermal decomposition temperature when compared with both pure PPC and the composites prepared from un-modified MMT. Dynamic mechanical analysis indicated that nano-scale OMMT dispersed well within PPC matrix and therefore enhanced the storage modulus of the composites.
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