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Template synthesis of LaMnO3+δ ordered nanowire arrays by converse diffusion or convection
Affiliation:1. Key Laboratory of Polymer, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People''s Republic of China;2. Chemistry Department of Lanzhou University, Lanzhou 730000, People''s Republic of China;1. Materials Chemistry Research Unit, Department of Chemistry and Center for Innovation in Chemistry, Khon Kaen University, Khon Kaen 40002, Thailand;2. Faculty of Science, Advanced Functional Material Research Cluster, Khon Kaen University, Khon Kaen 40002, Thailand;3. Materials Chemistry Research Unit, Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand;1. Department of Physics, Kangwon National University, Chuncheon 200-701, Republic of Korea;2. Korea Research Institute of Standards and Science, Daejeon 305-340, Republic of Korea;1. Materials Research Laboratory, Department of Physics, University of Peshawar, 25120, Pakistan;2. Department of Physics, Abdul Wali Khan University Mardan (AWKUM), 23200 Mardan, Pakistan;3. Department of Physics, Islamia College University, Peshawar 25120, Pakistan
Abstract:A method, whereby metal ions and precipitation reagents were transported in the nanochannels of anodic alumina membrane (AAM) templates by converse diffusion or convection and reacted in situ to form into one-dimensional nanostructure of the precursor, was developed. A high-aspect ratio nanowire array of the LaMnO3+δ was prepared by this method. Electron microscope images showed that the LaMnO3+δ nanowire array was abundant, uniformly distributed and well-ordered in large area. The individual nanowires are about 60 nm in diameter and their length corresponds to the thickness of the applied AAM template. The analysis of X-ray diffractions demonstrated that the LaMnO3+δ nanowires are pseudocubic with typical perovskite lattice parameter.
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