| Abstract: | Styrene‐butadiene rubber (SBR) nanocomposites with different organoclay contents (up to 15 phr) were prepared by a melt compounding procedure, followed by a compression‐molding step in which the SBR matrix was sulfur crosslinked. The vulcanizates were characterized in respect to their curing, mechanical and viscoelastic properties, and thermal stability. The optimum cure time decreased with increasing organoclay content. This effect was attributed to the ammonium modifier present in the organoclay, which takes part in the curing reaction acting like an accelerator. The results of mechanical test on the vulcanizates showed that the nanocomposites presented better mechanical properties than unfilled SBR vulcanizate, indicating the nanoreinforcement effect of clay on the mechanical properties of SBR/organoclay nanocomposites. The addition of organoclay did not significantly change the glass transition temperature. However, the heights of tan δ value at the glass transition temperature for the nanocomposites are lower than that of the unfilled SBR. This suggests a strong interaction between the organoclay and the SBR matrix as the molecular relaxation of the latter is hampered. The temperature at which 50% degradation occurs (T50) and the temperature when the degradation rate is maximum (DTGmax) showed an improvement in thermal stability, probably related to the uniform dispersion of organoclay. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 |
