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Nitrogen-containing microporous carbons prepared from anionic surfactant-melamine/formaldehyde composites
Authors:Yong-Rong Dong  Masaya Kodama  Korekazu Ueyama
Affiliation:a Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
b Energy Storage Materials Group, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569, Japan
Abstract:Nitrogen-containing microporous carbons have been synthesized by the carbonization of anionic surfactant-melamine/formaldehyde (MF) composites, which were themselves formed by an electrostatic organic-organic interaction. The carbons prepared from sodium dioctyl sulfosuccinate-MF and sodium dodecyl sulfate-MF mixtures have high surface area of 464 and 539 m2 g−1, respectively. The N/C molar ratios of the carbons are 0.11. The resultant carbons showed capacitances higher than 200 F g−1 in an acidic solution of 1 M H2SO4 at a scan rate of 1 mV s−1.
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