| 咪唑基多芳胺类化合物的合成 |
| |
| 引用本文： | 耿师科,郝占忠,马学林.咪唑基多芳胺类化合物的合成[J].化学试剂,2017,39(3). |
| |
| 作者姓名： | 耿师科 郝占忠 马学林 |
| |
| 作者单位： | 包头师范学院化学学院材料化学与物理重点实验室,内蒙古包头,014030 |
| |
| 基金项目： | 内蒙古自治区自然科学基金资助项目,包头师范学院青年基金资助项目 |
| |
| 摘 要： | 无氧条件下,环己烷作溶剂,以咪唑为酸性组分与芳香醛和芳香胺反应,通过多组分Mannich反应,“一锅法”合成7种新型咪唑基多芳胺类化合物,产率81％ ～88％.产物通过IR、1HNMR和元素分析确定.该方法具有操作简单、条件温和、产率高、选择性高等特点.
|
| 关 键 词： | 咪唑衍生物 Mannich反应 一锅法 |
Synthesis Multi Aromatic Amine Compounds with Imidazole |
| |
| GENG Shi-ke,HAO Zhan-zhong,MA Xue-lin.Synthesis Multi Aromatic Amine Compounds with Imidazole[J].Chemical Reagents,2017,39(3). |
| |
| Authors: | GENG Shi-ke HAO Zhan-zhong MA Xue-lin |
| |
| Abstract: | Under anaerobic conditions and cyclohexane as solvent,novel multi aromatic amine compounds were synthesized with imidazole,aromatic aldehydes and aromatic amines by three component " one pot " Mannich reaction.The yield reached 81％ ～88％.The products are confirmed by IR,1HNMR and elemental analysis.This process has advantages of simple,mild conditions,high yield and high selectivity. |
| |
| Keywords: | imidazole derivatives Mannich reaction one pot |
| 本文献已被 万方数据 等数据库收录！ |
|
