| 精确合成多溴代二苯醚类化合物 |
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| 引用本文： | 沈宏,崔凯.精确合成多溴代二苯醚类化合物[J].化学试剂,2017,39(3). |
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| 作者姓名： | 沈宏 崔凯 |
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| 作者单位： | 1. 江苏开放大学环境与生态学院,江苏南京,210089;2. 南京大学金陵学院化学与生命科学学院,江苏南京,210036 |
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| 基金项目： | 江苏开放大学校“十二五”规划2013年度课题项目，江苏省高校自然科学基金项目，南京大学污染控制与资源化研究国家重点实验室开放课题与访问学者项目，2016年度江苏省高校“青蓝工程”项目(苏教师 |
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| 摘 要： | 用间氯过氧苯甲酸和三氟甲磺酸作为酸性氧化体系,以多种溴代碘苯及溴代苯合成了溴代二苯基碘盐.再以其与溴代苯酚在碱性条件下反应,精确合成各种多溴代二苯醚.该方法简便、反应条件温和、后处理简单、产品纯度好、收率高.
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| 关 键 词： | 精确合成 溴代二苯醚 溴代二苯基碘盐 间氯过氧苯甲酸 三氟甲磺酸 |
Accurate Synthesis of Polybrominated Diphenyl Ethers |
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| SHEN Hong,CUI Kai.Accurate Synthesis of Polybrominated Diphenyl Ethers[J].Chemical Reagents,2017,39(3). |
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| Authors: | SHEN Hong CUI Kai |
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| Abstract: | A series of polybrominated diphenyliodonium trifluoromethanesulfonic salt were synthesized from brominated iodobenzene and brominated benzene catalyzed by m-chloroperoxybenzoic acid and trifluoromethanesulfonic acid.Then corresponding polybrominateddiphenyl ethers were accurately synthesized with them and brominated phenol in alkaline condition.The advantages of the procedure is mild reaction condition,easy operation,simple after-treatment,high yield and purity of products. |
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| Keywords: | accurate synthesis polybrominated diphenyl ethers polybrominated diphenyliodonium trifluoromethanesulfonic salt m-chloroperoxybenzoic acid trifluoromethanesulfonic acid |
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