| 合成3-甲氧基丙烯酸甲酯的新方法 |
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| 引用本文： | 吴清来,鲁东飞. 合成3-甲氧基丙烯酸甲酯的新方法[J]. 化学试剂, 2017, 39(4). DOI: 10.13822/j.cnki.hxsj.2017.04.020 |
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| 作者姓名： | 吴清来 鲁东飞 |
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| 作者单位： | 长江大学农学院,湖北荆州,434025 |
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| 摘 要： | 以乙烯基甲醚和三氯乙酰氯为原料,经加成-消除反应、加成反应、卤仿反应及消除反应合成标题化合物,总收率为56.5％.该合成方法原料廉价且简单易得、反应条件温和、操作简单安全,有工业产业化应用前景.
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| 关 键 词： | 3-甲氧基丙烯酸甲酯 乙烯基甲醚 三氯乙酰氯 合成 |
New Synthetic Method of Methyl 3-Methoxyacrylate |
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| WU Qing-lai,LU Dong-fei. New Synthetic Method of Methyl 3-Methoxyacrylate[J]. Chemical Reagents, 2017, 39(4). DOI: 10.13822/j.cnki.hxsj.2017.04.020 |
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| Authors: | WU Qing-lai LU Dong-fei |
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| Abstract: | A new synthetic method of methyl 3-methoxyacrylate was established in this work.Methyl 3-methoxyacrylate was obtained from methyl vinyl ether and trichloroacetyl chloride as starting material via addition-elimination reaction,elimination reaction,haloform reaction and elimination reaction.The total yield is 56.5％.In this method,material is cheap and easily available,reaction conditions are mild,the operation is simple and safe,and it has the prospect of industrial application. |
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| Keywords: | methyl 3-methoxyacrylate methyl vinyl ether trichloroacetyl chloride synthesis |
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