Impact of the Relationship between Phase Change Temperature and Boundary Temperature on the Thermal Performance of a PCM Wall and the Presentation of PCM Thermal Performance Indexes

In the composite phase change material (PCM) building envelope, the matching relationship between the phase change temperature of the PCM and the wall's boundary temperature significantly affects the energy storage performance of the PCM building envelope. In this paper, a type of concrete hollow block with a typical structure and a common PCM were adopted to produce multiform composite PCM hollow blocks, and the temperature changing hot chamber method was performed to test the thermal performance of the hollow block walls under different temperature conditions. New indexes were proposed for the thermal performance evaluation of the PCM wall. Meanwhile, combined with experimental data, the effective heat capacity model and the enthalpy model were used to analyze the effect of correlations concerning how the relationship between phase change temperature and wall's boundary temperature influenced the thermal performance of PCM wall. Three main impact factors related to temperature were obtained through the analysis. In addition, approaches for improving the thermal performance of a composite PCM wall were put forward. This paper provides the theoretical basis, data reference and practical instruction for the proper use of a PCM wall and ways for improving the thermal performance of a composite PCM wall.