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Vapor‐phase polymerization of pyrrole on flexible substrate at low temperature and its application in heat generation
Authors:Songmin Shang  Xiaoming Yang  Xiao‐ming Tao  Song Song Lam
Affiliation:1. Institute of Textiles and Clothing, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, PR China;2. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Jiangsu Province, Suzhou 215123, PR China
Abstract:The vapor‐phase polymerization of pyrrole to form conducting polypyrrole (PPy) films was applied to coat flexible poly(ethylene terephthalate) (PET) fabrics. A PPy‐coated PET fabric surface resistance of 200–20 000 Ω□?1 was obtained. The polymerization conditions, such as the concentration of oxidant and the reaction time and temperature, were systematically investigated. The coated fabric samples exhibited increasing temperatures when subjected to a fixed DC voltage. This result indicates the potential of these PPy‐coated fabric materials for heating applications. Copyright © 2009 Society of Chemical Industry
Keywords:conducting polymer  heat generation  surface modification  vapor‐phase polymerization
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