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Evaluation of the Effectiveness of New Compatibilizers Based on EBAGMA‐LDPE and EBAGMA‐PET Masterbatches for LDPE/PET Blends
Authors:Aida Benhamida  Mustapha Kaci  Sossio Cimmino  Clara Silvestre  Donatella Duraccio
Affiliation:1. Laboratoire des Matériaux Organiques, Faculté de la Technologie, Université Abderrahmane Mira, Bejaia 06000, Algeria;2. Istituto di Chimica e Tecnologia dei Polimeri (ICTP) – CNR, Via Campi Flegrei 34, 80078 Pozzuoli, NA, Italy
Abstract:The present paper is aimed to evaluate the efficiency of two masterbatches, i.e., EBAGMA/LDPE (MB1) and EBAGMA/PET (MB2) with 50/50 w/w composition, prepared by melt mixing and used as new compatibilizers for blends of LDPE/PET. The morphology, the mechanical and the thermal properties of LDPE/PET/MB1 and LDPE/PET/MB2 ternary blends have been investigated. Morphological investigation by SEM of LDPE/PET/MB1 ternary blends showed a finer dispersion of PET in LDPE matrix with a better interfacial adhesion compared to those of both LDPE/PET/MB2 and binary LDPE/PET blends. The results also indicated a substantial improvement in both elongation at break and impact strength, while the Young's modulus decreased. Moreover, the thermal properties showed a decrease of the crystallization phenomena of PET in LDPE/PET/MB1 blend, thus confirming the good dispersion of PET particles into the continuous phase of LDPE matrix, leading to the conclusion that MB1 could be an efficient compatibilizer for LDPE/PET system.
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Keywords:blends  compatibilization  EBAGMA  LDPE  PET
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