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Precipitation path of secondary phases during solidification of the Co–25.5%Cr–5.5%Mo–0.26%C alloy
Authors:L E Ramírez  M Castro  M Mndez  J Lacaze  M Herrera  G Lesoult
Affiliation:

a Centro de Investigación y de Estudios Avanzados del IPN, Cinvestav Saltillo, Carr. Saltillo-Monterrey km 13, A. Postal 663, 25000 Saltillo, Coahuila, Mexico

b CIRIMAT, UMR CNRS/INPT/UPS 5085, ENSIACET, 31077, Toulouse Cedex 4, France

c Laboratoire de Science et Génie des Matériaux Métalliques, UMR CNRS 7584, ENSMN, Parc de Saurupt, 54042, Nancy Cedex, France

Abstract:The solidification of the alloy ASTM F-75 ends with sigma phase formation instead of M7C3 carbide as presumed from literature. The M23C6 carbide observed in cast specimens precipitates from the sigma phase (σ) according to the global reaction σ+C→M23C6 over the range 1403–1303 K. Additionally, lamellar carbides appear below 1262 K for cooling rates lower than 35 K/min.
Keywords:Solidification  Biomaterials  Casting  Carbides
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