Polyamides based on diamines containing aryloxy groups: Structure-property relationships |
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Authors: | Sheng-Huei Hsiao Yu-Jen Chen |
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Affiliation: | (1) Department of Chemical Engineering, Tatung University, Taipei, 10451, Taiwan |
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Abstract: | Aromatic polyamides containing different numbers of p-oxyphenylene groups and different catenated positions in the benzene
rings were prepared from terephthalic acid (TPA) and isophthalic acid (IPA) with various aryloxy-containing diamines by means
of the phosphorylation polycondensation reaction. Most of the polyamides were moderately to highly crystalline, as indicated
by X-ray diffraction and DSC measurements. Polyisophthalamides were readily soluble in polar amide-type solvents such as N-methyl-2-pyrrolidone (NMP) and N,N-dimethylacetamide (DMAc). Some non-crystalline polyamides could afford tough films by solution casting. Most polyisophthalamides
revealed discernible glass transition on their DSC curves, and their Tg values were recorded in the range of 215–238 °C. No discernible glass transitions were observed for the polyamides of TPA
by DSC. The thermal stability of these polymers did not show clear dependence on the structure of the diacid or the diamine.
In addition, a series of polyamides having pendant groups was synthesized from the polycondensation of TPA and IPA with 1,4-bis(4-aminophenoxy)benzene
and its derivatives with methyl, tert-butyl, or phenyl substituent on the central benzene ring. In most cases, the incorporation of pendant groups generally resulted
in an enhanced solubility and a decreased Tg and crystallinity. |
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Keywords: | Polyamides Terephthalic acid Isophthalic acid Ether-diamines Structure-property relationships |
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