Particulate forms of radium and barium in uranium mine waste waters and receiving river waters

A method of selective dissolution was used for analysis of particulate forms of radium and barium in a system consisting of uranium mine waste waters purified by coprecipitation with barium sulphate and of adjacent river waters. Four particulate forms of both the elements were distinguished: “loosely bound”, “acid soluble”, Ba(Ra)SO₄ and “in crystalline detritus”. It was found that the distribution of radium and barium between dissolved and particulate forms in waste waters depended on the time interval elapsing between the sampling and membrane filtration of the waters. No such dependence occurred in river water. The main particulate form of radium and barium in the system was Ba(Ra)SO₄. River water upstream of the mine water discharge contained radium mainly in “acid soluble” form or “in crystalline detritus” and barium as BaSO₄ or “crystalline detritus”. In unpurified mine effluents, a large part of radium and barium was present as “crystalline detritus”. Abundance of the “loosely bound” form was very low in all the samples analyzed. The bond of radium in bottom sediments was approximately the same as that in the solids suspended in waste waters. Suitability and accuracy of the selective dissolution method for analysis of surface and waste waters has been demonstrated by the analysis of the results and by radiotracer experiments.