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Novel photorefractive sol-gel materials
Authors:Bruno Darracq, Fr  d  ric Chaput, Khalid Lahlil, Jean-Pierre Boilot, Yves Levy, Valerie Alain, Lionel Ventelon,Mireille Blanchard-Desce
Affiliation:

a Groupe d'Optique Non Linéaire, Institut d'Optique Théorique et Appliquée, URA CNRS 14, Bâtiment 503, B.P. 147, 91403, Orsay Cedex, France

b Groupe de Chimie du Solide, Laboratoire de Physique de la Matière Condensée, URA CNRS 1254D, Ecole Polytechnique, 91128, Palaiseau, France

c Département de Chimie, Ecole Normale Supérieure, URA CNRS 1679, 24 rue Lhomond, 75231, Paris, France

Abstract:We have developed new photorefractive media based on hybrid organic-inorganic materials containing a charge transporting (CT) molecule either as side-chain or main-chain substituents on the silica backbone. Second order nonlinear optical (NLO) chromophores were introduced either as side chain or as guest units. These materials were prepared by the sol-gel process in the form of thin films of a few μm-thick. NLO and photorefractive properties have been evaluated using electro-optic measurements, two beam coupling experiments and photoconductivity measurements.
Keywords:
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