Electrolysis of coal slurries to produce hydrogen gas: Effects of different factors on hydrogen yield |
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Authors: | Arif Hesenov,Bahar Meryemo?luOkan Iç ten |
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Affiliation: | Department of Chemistry, Çukurova University, Arts and Sciences Faculty, Adana 01330, Turkey |
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Abstract: | The study was aimed to investigate the effects of different factors (such as acid concentration, cell potential, temperature, coal types, and geometric area of the membrane) on the coal slurry electrolysis and hydrogen evolution. It was observed that all of the above factors affected hydrogen production upon completion of the electrolysis. The results revealed that an increase in the initial acid concentration up to 5.0 M brought about an increase in the current density and hydrogen evolution. However, the higher the acid concentration was taken (>7.0 M) then the lower the current density and hydrogen evolution were, which resulted in significant change due to the agglomeration of coal samples and stuck on the electrode surface.Furthermore, the CO2 evolution (14 ml) was observed only at high temperature (100 °C) and high (2.0 V) cell potential when the H2 amount was 776 ml. The coal type was observed to have influenced the electrolysis. |
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Keywords: | Hydrogen production Coal oxidation Electrochemical gasification |
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