Thermodynamics of Melting of Polymers at High Pressures |
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| Authors: | V F Skorodumov E M Pokrovskii A V Motavkin |
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| Affiliation: | (1) Moscow State Textile University, Moscow, Russia;(2) Russian Federation State Science Center, L. Ya. Karpov Scientific-Research Institute of Physical Chemistry, Russia |
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| Abstract: | Equations that allow determining the melting point, change in volume, and other thermodynamic parameters of melting of polymers at high pressure are proposed based on the statistical-thermodynamic theory of melting of polymers. The good agreement of the predictions of the theory and the experimental data for polyethylene is demonstrated.__________Translated from Khimicheskie Volokna, No. 1, pp. 29–32, January–February, 2005. |
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