Sensitive detection of mercury (II) ion using water-soluble captopril-stabilized fluorescent gold nanoparticles |
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Authors: | Jiu-Ju Feng Hong Huang Wei-Jie Chen Jian-Rong Chen Hong-Jun Lin Ai-Jun Wang |
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Affiliation: | College of Geography and Environmental Science, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, China |
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Abstract: | In our work, a simple, facile, and green method was developed for the synthesis of water-soluble and well-dispersed fluorescent gold nanoparticles (Au NPs) within 5 min, using captopril as a capping agent. The as-prepared Au NPs showed strong emission at 414 nm, with a quantum yield of 5.5%. The fluorescence of the Au NPs can be strongly quenched by mercury (II) ion (Hg2 +) due to the stronger interactions between thiolates (RS?) and Hg2 +. It was applied to the detection of Hg2 + in water samples in the linear ranges of 0.033–0.133 μM and 0.167–2.500 μM, with a detection limit of 0.017 μM. Therefore, the as-prepared Au NPs can meet the requirement for monitoring Hg2 + in environmental samples. |
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