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1,2-环己二醇在溶剂中的溶解度
引用本文:周彩荣,王海峰,蒋登高. 1,2-环己二醇在溶剂中的溶解度[J]. 中国化学工程学报, 2005, 13(4)
作者姓名:周彩荣  王海峰  蒋登高
作者单位:Institute of Chemical Engineering,Zhengzhou University,Institute of Chemical Engineering,Zhengzhou University,Institute of Chemical Engineering,Zhengzhou University Zhengzhou 450002,China,Zhengzhou 450002,China,Zhengzhou 450002,China
摘    要:1 INTRODUCTION The solubility of solid in liquids is an excellent tool to investigate solute-solvent intermolecular forces in the liquid state. In this work the solubility of trans-1,2-cyclohexanediol in some polar solvents (wa- ter, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, and ethyl acrylate) was mea- sured at temperatures ranging from about 300 K to 330 K, using a modification of the experimental tech- nique of laser monitoring observation system. So…


Solubility of trans-1,2-Cyclohexanediol in Some Solvents
ZHOU Cairong,WANG Haifeng,Jiang Denggao. Solubility of trans-1,2-Cyclohexanediol in Some Solvents[J]. Chinese Journal of Chemical Engineering, 2005, 13(4)
Authors:ZHOU Cairong  WANG Haifeng  Jiang Denggao
Affiliation:Institute of Chemical Engineering , Zhengzhou University, Zhengzhou 450002, China;Institute of Chemical Engineering , Zhengzhou University, Zhengzhou 450002, China;Institute of Chemical Engineering , Zhengzhou University, Zhengzhou 450002, China
Abstract:The solubility of trans-1,2-cyclohexanediol in water, methyl acetate, acetic ester, propyl acetate, butyl acetate, methyl acrylate, ethyl acrylate, 2-pentanone and acetoacetic ester was measured at temperatures ranging from about 300 K to 330K, using a modification of the experimental technique of laser monitoring observation system. The solubilities were calculated by λh method, in which new parameters were introduced to express the activity coefficients of trans-1,2-cyclohexanediol, and determined from the experimental data. The new parameters provide good calculated results. The experimental data were also correlated with a simple model, and results were compared with present λh model.
Keywords:solid- liquid equilibrium  solubility  trans-1  2-cyclohexanediol  acetate  acrylate  acetoacetate
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