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环保型阻燃增强聚丙烯的研制
引用本文:张治华,魏玲统.环保型阻燃增强聚丙烯的研制[J].塑料助剂,2009(5):22-23,32.
作者姓名:张治华  魏玲统
作者单位:1. 青岛华舜工贸有限公司,胶州,266300
2. 青岛怡和华润进出口有限公司,青岛,266071
摘    要:以氮-磷系阻燃剂,马来酸酐接枝聚丙烯(PP-g-MA)与阻燃用有机改性纳米蒙脱土(ONMMT-FR)的母粒作相容剂和阻燃协效剂、玻璃纤维增强剂,对聚丙烯(PP)进行阻燃增强改性,制得的纳米复合材料阻燃性达到UL-94 V-0级(1.6 mm),且低烟,无熔滴,拉伸强度40.8~41.5 MPa,弯曲强度68.2~70.5 MPa,缺口冲击强度8.48~8.95 kJ/m2,热变形温度159~160℃(0.45 MPa下)。

关 键 词:氮-磷系阻燃剂  马来酸酐接枝聚丙烯  纳米蒙脱土  增强塑料  聚丙烯  复合材料

Preparation of Enviroment Friendly Flame Retarded and Reinforced Polypropylene
Zhang Zhi-hua,Wei Ling-tong.Preparation of Enviroment Friendly Flame Retarded and Reinforced Polypropylene[J].Plastic Additives,2009(5):22-23,32.
Authors:Zhang Zhi-hua  Wei Ling-tong
Affiliation:Zhang Zhi-hua Wei Ling-tong(1.Qindao Huashun Industry & Trade Company Co.,Ltd.,Jiaozhou,266300;2.Qindao Yihehuarun Imports & Exports Company Co.,Ltd.,Qindao,266071)
Abstract:A nano-composite was prepared,which contain a matrix resin of PP,a flame retardant of nitrogen-phosphorus system,and a organic modified nano-montmorillonite(ONMMT) as flame retardant anxiliary agent and PP-g-MA as compatibilizer,and is reinforced with glass fibre.The flame retarded PP composite was reaches to flamability of UL-94 V-0(1.6 mm),and which is low smoke,no melt dropping,offer tensile strength of 40.8~41.5 MPa,bending strength of 68.2~70.5 MPa,notched impact strength of 8.48~8.95 kJ/m2,heat distortion temperature of 159~160 ℃(at 0.45 MPa).
Keywords:nitrogen-phosphornus flame retardant  polypropylene grafed by maleic anhydriede  nano-montmonllonite  reinforced plastic  polypropylene  composite
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