| 主链掺杂原子聚硅烷的研究进展 |
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| 引用本文： | 崔孟忠,唐小真.主链掺杂原子聚硅烷的研究进展[J].有机硅材料,2005,19(4):26-31. |
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| 作者姓名： | 崔孟忠 唐小真 |
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| 作者单位： | 1. 烟台大学化学生物理工学院,山东烟台,264005
2. 上海交通大学化学化工学院,上海,200240 |
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| 摘 要： | 介绍了新型有机硅聚合物——主链掺杂原子聚硅烷的研究概况。在介绍了主链掺杂氧原子聚硅烷的两种有效合成方法、开环聚合机理研究进展的同时，简要介绍了聚硅烷或其低聚物掺杂其它原子的新型化合物；讨论了此类聚合物的相关性能及其结构形态，并展望了此类聚合物的应用前景。
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| 关 键 词： | 聚硅烷 聚硅氧烷 环硅杂原子化合物 全甲基主链掺杂聚硅烷 |
| 文章编号： | 1009-4369(2005)04-0026-06 |
| 修稿时间： | 2004年11月26 |
Progress on organic polysilane interrupted by heteroatoms |
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| CUI Meng-Zhong,TANG Xiao-zhen.Progress on organic polysilane interrupted by heteroatoms[J].Silicone Material,2005,19(4):26-31. |
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| Authors: | CUI Meng-Zhong TANG Xiao-zhen |
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| Affiliation: | CUI Meng-zhong~1,TANG Xiao-zhen~2 |
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| Abstract: | A novel type of silicone polymer, organic polysilane interrupted by heteroatoms was introduced. After introduced two kinds of synthesis method of organic polysilane interrupted by heteroatoms and progress of polymerization mechanism of ring-opening, a new compound with polysilane and its oligomer interrupted by other heteroatoms was introduced. Some discussions were devoted to the characterization, thermal properties and morphology of the polymer, its future was also prospected. |
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| Keywords: | polysilanes polysiloxanes cyclic silaethers polysilanes interrupted by heteroatoms |
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