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Leaching Gold Using Oxidation Products of Elemental Sulfur in Ca(OH)2 Solution Under Oxygen Pressure
作者姓名:方兆珩  韩宝玲
作者单位:Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China
基金项目:Supported by the National Natural Science Foundation of China (No.: 59674025)
摘    要:A gold leaching process by using in situ oxidation products of added elemental sulfur in Ca(OH)2 solution was investigated. A gold concentrate containing 45 g/t Au was tested and 85%~87% of gold were leached. The leached gold depends mainly on the initial molar ratio of elemental sulfur to the hydroxyl ion, the consumption of oxygen and the reaction temperature. Adding some surfactants, such as lignosulfonic calcium, at lower concentration increased the leached Au but at higher concentration decreased it. Both of thermodynamic analysis and experimental results show that thiosulfate is the major complexing agent for gold in the process.

关 键 词:gold  leaching  elemental  sulfur  alkaline  solution  oxygen  pressure  thiosulfate

Leaching Gold Using Oxidation Products of Elemental Sulfur in Ca(OH)2 Solution under Oxygen Pressure
FANG Zhao-heng,Han Bao-ling.Leaching Gold Using Oxidation Products of Elemental Sulfur in Ca(OH)2 Solution Under Oxygen Pressure[J].Chinese Journal of Process Engineering,2002,2(3):230-234.
Authors:FANG Zhao-heng  Han Bao-ling
Abstract:A gold leaching process by using in situ oxidation products of added elemental sulfur in Ca(OH)2 solution was investigated. A gold concentrate containing 45 g/t Au was tested and 85%~87% of gold were leached. The leached gold depends mainly on the initial molar ratio of elemental sulfur to the hydroxyl ion, the consumption of oxygen and the reaction temperature. Adding some surfactants, such as lignosulfonic calcium, at lower concentration increased the leached Au but at higher concentration decreased it. Both of thermodynamic analysis and experimental results show that thiosulfate is the major complexing agent for gold in the process.
Keywords:gold leaching  elemental sulfur  alkaline solution  oxygen pressure  thiosulfate
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