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阳离子改性酶解豌豆淀粉及其在玻纤浸润剂中的应用研究
引用本文:孙欢欢 雷洪 霍冀川. 阳离子改性酶解豌豆淀粉及其在玻纤浸润剂中的应用研究[J]. 玻璃, 2014, 0(3): 34-39
作者姓名:孙欢欢 雷洪 霍冀川
作者单位:[1]西南科技大学生物质材料教育部工程研究中心,绵阳市621010 [2]西南科技大学材料科学与工程学院,绵阳市621010 [3]西南科技大学分析测试中心,绵阳市621010
基金项目:基金项目:国家高技术研究发展计划863项目基金(批准号:2009AA035002);四川省玻纤集团有限公司横向项目(13zh0054).
摘    要:以豌豆淀粉为原料,经酶解处理后,再将所得产品与3-氯-2-羟丙基氯化铵进行阳离子化反应,制备玻璃纤维浸润剂用淀粉成膜剂。通过单因素试验考察了氢氧化钠的加入以及酶解时间对黏度、表面张力和成膜性的影响。当酶解时间为20 h,糊化时加氢氧化钠,可降低成膜剂溶液的表面张力和黏度,所得成膜剂成膜性能好,可作为成膜剂用于玻璃纤维浸润剂体系。

关 键 词:酶解  浸润剂  阳离子淀粉  表面张力

Study of The Cationic Modification of Pea Starch and The Application of The Product in Glass Fiber Sizing Agent
Sun Huanhuan,Lei Hong,Huo Jichuan. Study of The Cationic Modification of Pea Starch and The Application of The Product in Glass Fiber Sizing Agent[J]. Class, 2014, 0(3): 34-39
Authors:Sun Huanhuan  Lei Hong  Huo Jichuan
Affiliation:1. Engineering Research Center of Biomass Materials, Ministry of Education, Southwest University of Science and Technology: 2. College of Materials Science and Engineering, Southwest University of Science and Technology; 3. Analytical and testing center, Southwest University of Science and Technology, Mianyang, 621010 )
Abstract:TPea starch was used as the raw material to produce film-forming agent for glass fiber sizing agent in this study. The starch was firstly modified with isoamylase and then reacted with 3-chloro-2- hydroxypropyl ammonium chloride. The influence of the enzyme-hydrolysis time and sodium hydroxide on the viscosity, surface tension and film-forming property of the modified starch were studied. When the enzyme-hydrolysis time was 20 h and adding sodium hydroxide when gelatinization, the surface tension and viscosity of the filmforming agent suspension could be reduced. The film-forming agent with good film-forming property has the potential to be applied in glass fibre sizing agent.
Keywords:Enzyme hydrolysis   Sizing agent   Cationic starch   Surface tension
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