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水溶性含氟丙烯酸酯乳液的合成研究进展
引用本文:梁军艳,和玲,于澄洁.水溶性含氟丙烯酸酯乳液的合成研究进展[J].化学与粘合,2006,28(6):419-423.
作者姓名:梁军艳  和玲  于澄洁
作者单位:西安交通大学,理学院应用化学系,陕西,西安,710049;西安石油大学,图书馆,陕西,西安,710065
摘    要:含氟丙烯酸酯类聚合物因具有突出的成膜性能及耐老化性能而成为优良的成膜材料。其中,水溶性含氟丙烯酸酯乳液的合成研究,具有广泛的单体种类,聚合方式简单多样,在涂料领域受到了广泛的应用和关注。选择合适的乳液共聚单体及聚合工艺,不仅能够根据实际需要调节含氟聚合物的分子结构,而且可以获得最佳含氟量,以满足特殊性能需要的含氟丙烯酸酯乳液。综述了水溶性含氟丙烯酸酯乳液的聚合方法、常用含氟单体和非氟单体以及改性研究进展。

关 键 词:含氟丙烯酸酯乳液  共聚物  乳液聚合  含氟单体
文章编号:1001-0017(2006)06-0419-05
收稿时间:2006-05-25
修稿时间:2006-05-25

Development of the Synthesis of Aqueous Fluorinated Acrylate Emulsion
LIANG Jun-yan,HE Ling,YU Cheng-jie.Development of the Synthesis of Aqueous Fluorinated Acrylate Emulsion[J].Chemistry and Adhesion,2006,28(6):419-423.
Authors:LIANG Jun-yan  HE Ling  YU Cheng-jie
Abstract:Fluorinated acrylate polymers were well known film -forming materials for their excellent film - forming properties and aging resistance. The aqueous fluorinated acrylate emulsion was widely applied and concerned in coating industry for its various monomer species and simple polymerization method. Selecting proper monomer and polymerization technique for emulsion polymerization could adjust the molecular structure of fluorinated polymer, and obtain the optimal fluorine content to meet the requirement of fluorinated acrylate emulsion with special performance. Typical polymerization methods, fluorinated monomers, non fluorine monomer and the progress in the study on modification of aqueous fluorinated acrylate emulsion were introduced in this paper.
Keywords:Fluorinated acrylate emulsion  copolymers  emulsion polymerization  fluorinated monomer
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