The effect of current density and thickness of the active mass upon the corrosion rate of the spines of lead-acid battery plates |
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Authors: | T Rogatchev G Papazov D Pavlov |
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Affiliation: | Central Laboratory of Electrochemical Power Sources, Bulgarian Academy of Sciences, 1040 Sofia Bulgaria |
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Abstract: | The effect of current density and the thickness of the active mass upon the corrosion of the spines of tubular lead-acid batteries has been determined by measuring the corrosion rate by the weight loss method. The presence of antimony in the alloy decreases the overvoltage of the corrosion reaction. Study of electrodes of different active mass layer thickness shows that with increase in thickness the corrosion rate decreases. If the thickness is above 3 mm, the corrosion rate remains constant, and is affected only by the nature of the alloy. The density of the active mass does not affect the corrosion behaviour of the electrodes. The experimental results confirm the validity of the oxygen corrosion model. |
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